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The following term was not found in PubMed: -triazacyclopentene
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[(E)-2-(3,5-Dibromo-2-oxidobenzyl-ideneamino)-3-(4-hydroxy-phen-yl)propionato-kappaO,N,O'](dimethyl-formamide-kappaO)copper(II).
Tan MX, Chen ZF, Neng Z, Liang H. Tan MX, et al. Acta Crystallogr Sect E Struct Rep Online. 2008 Mar 29;64(Pt 4):m601-2. doi: 10.1107/S1600536808007915. Acta Crystallogr Sect E Struct Rep Online. 2008. PMID: 21202044 Free PMC article.
Each Cu(II) atom is coordinated by two O atoms and one N atom from the tridentate ligand L(2-) [LH(2) = (E)-2-(3,5-dibromo-2-hydroxy-benzyl-idene-amino)-2-(4-hydroxy-phenyl)acetic acid] and the O atom of a dimethyl-formamide mol-ecule to give a …
Each Cu(II) atom is coordinated by two O atoms and one N atom from the tridentate ligand L(2-) [LH(2) = (E)-2-(3 …
[(2S)-2-(3,5-Dichloro-2-oxidobenzyl-ideneamino)-3-(4-hydroxy-phen-yl)propionato-kappaO,N,O'](dimethyl-formamide-kappaO)copper(II).
Tan MX, Chen ZF, Neng Z, Liang H. Tan MX, et al. Acta Crystallogr Sect E Struct Rep Online. 2008 Mar 29;64(Pt 4):m599-600. doi: 10.1107/S1600536808007939. Acta Crystallogr Sect E Struct Rep Online. 2008. PMID: 21202043 Free PMC article.
In the title complex, [Cu(C(16)H(11)Cl(2)NO(4))(C(3)H(7)NO)] , the Cu(II) atom is coordinated by two O atoms and one N atom from the tridentate ligand L(2-) {LH(2) = (2S)-[2-(3,5-dichloro-2-hydroxy-benzyl-idene)-imino]-3-(4-hydroxy-phenyl)propio …
In the title complex, [Cu(C(16)H(11)Cl(2)NO(4))(C(3)H(7)NO)] , the Cu(II) atom is coordinated by two O atoms and one N atom from the trident …
An Alkylpyrazine Synthesis Mechanism Involving l-Threonine-3-Dehydrogenase Describes the Production of 2,5-Dimethylpyrazine and 2,3,5-Trimethylpyrazine by Bacillus subtilis.
Zhang L, Cao Y, Tong J, Xu Y. Zhang L, et al. Appl Environ Microbiol. 2019 Nov 27;85(24):e01807-19. doi: 10.1128/AEM.01807-19. Print 2019 Dec 15. Appl Environ Microbiol. 2019. PMID: 31585995 Free PMC article.
TDH catalyzes the oxidation of l-threonine. The product of this reaction is l-2-amino-acetoacetate, which is known to be unstable and can decarboxylate to form aminoacetone. ...This study revealed the substrate, intermediates, and related enzymes for the synthesis o …
TDH catalyzes the oxidation of l-threonine. The product of this reaction is l-2-amino-acetoacetate, which is known to be unsta …
Poly[[(μ(3)-5,6-dicarboxy-bicyclo-[2.2.2]oct-7-ene-2,3-dicarboxyl-ato)(1,10-phenanthroline)copper(II)] monohydrate].
Liu YY, Zhuo YJ, Li XQ, Ma JC. Liu YY, et al. Acta Crystallogr Sect E Struct Rep Online. 2008 Nov 22;64(Pt 12):m1590. doi: 10.1107/S1600536808037999. Acta Crystallogr Sect E Struct Rep Online. 2008. PMID: 21581190 Free PMC article.
In the title compound, {[Cu(C(12)H(10)O(8))(C(12)H(8)N(2))].H(2)O}(n), the Cu(II) ion is five-coordinated by two N atoms from one phenanthroline ligand and three O atoms from three different H(2)L(2-) anions (H(4)L is bicyclo-[2.2.2]oct-7-ene-2,3,5 …
In the title compound, {[Cu(C(12)H(10)O(8))(C(12)H(8)N(2))].H(2)O}(n), the Cu(II) ion is five-coordinated by two N atoms from one phenanthro …
New Transition Metal Coordination Polymers Derived from 2-(3,5-Dicarboxyphenyl)-6-carboxybenzimidazole as Photocatalysts for Dye and Antibiotic Decomposition.
Wu Y, Zhong W, Wang X, Wu W, Muddassir M, Daniel O, Raj Jayswal M, Prakash O, Dai Z, Ma A, Pan Y. Wu Y, et al. Molecules. 2023 Oct 28;28(21):7318. doi: 10.3390/molecules28217318. Molecules. 2023. PMID: 37959737 Free PMC article.
Herein, three different coordination polymers with compositions [Ni(HL)(H(2)O)(2).1.9H(2)O] (1), [Mn(3)(HL)(L)(mu(3)-OH)(H(2)O)(phen)(2).2H(2)O] (2), and [Cd(HL)(4)(H(2)O)].H(2)O (3) (H(3)L = 2-(3,5-dicarboxyphenyl)-6-carboxybenzimidazole; phen = 1,10- …
Herein, three different coordination polymers with compositions [Ni(HL)(H(2)O)(2).1.9H(2)O] (1), [Mn(3)(HL)(L)(mu(3)-OH)(H(2)O)(phen)(2).2H( …
Nacnac-Cobalt-Mediated P4 Transformations.
Spitzer F, Graßl C, Balázs G, Mädl E, Keilwerth M, Zolnhofer EM, Meyer K, Scheer M. Spitzer F, et al. Chemistry. 2017 Feb 21;23(11):2716-2721. doi: 10.1002/chem.201605451. Epub 2017 Jan 25. Chemistry. 2017. PMID: 28032678 Free PMC article.
The products 2 and 3 can be obtained selectively by an one-electron reduction of their neutral precursors 5 a and 6, respectively. The electrochemical behaviour of 2, 3, 5 a, and 6 is monitored by cyclic voltammetry and their magnetism is examined by SQUID me …
The products 2 and 3 can be obtained selectively by an one-electron reduction of their neutral precursors 5 a and 6, respectively. The elect …
Synthesis, Electrochemistry, and Single-Molecule Conductance of Bimetallic 2,3,5,6-Tetra(pyridine-2-yl)pyrazine-Based Complexes.
Davidson R, Liang JH, Costa Milan D, Mao BW, Nichols RJ, Higgins SJ, Yufit DS, Beeby A, Low PJ. Davidson R, et al. Inorg Chem. 2015 Jun 1;54(11):5487-94. doi: 10.1021/acs.inorgchem.5b00507. Epub 2015 May 14. Inorg Chem. 2015. PMID: 25974862 Free article.
The ligands 4'-(4-(methylthio)phenyl)-2,2':6',2"-terpyridine (L(1)), 4'-((4-(methylthio)phenyl)ethynyl)- 2,2':6',2"-terpyridine (L(2)), and bis(tridentate) bridging ligand 2,3,5,6-tetra(pyridine-2-yl)pyrazine (tpp) were used to prepare the compl …
The ligands 4'-(4-(methylthio)phenyl)-2,2':6',2"-terpyridine (L(1)), 4'-((4-(methylthio)phenyl)ethynyl)- 2,2':6',2"-terpyridine (L( …
Strong metal-metal coupling in mixed-valent intermediates [Cl(L)Ru(mu-tppz)Ru(L)Cl]+, L = beta-diketonato ligands, tppz = 2,3,5,6-tetrakis(2-pyridyl)pyrazine.
Kundu T, Schweinfurth D, Sarkar B, Mondal TK, Fiedler J, Mobin SM, Puranik VG, Kaim W, Lahiri GK. Kundu T, et al. Dalton Trans. 2012 Nov 21;41(43):13429-40. doi: 10.1039/c2dt31763j. Dalton Trans. 2012. PMID: 23007666
Five diruthenium(II) complexes [Cl(L)Ru(mu-tppz)Ru(L)Cl] (1-5) containing differently substituted beta-diketonato derivatives (1: L = 2,4-pentanedionato; 2: L = 3,5-heptanedionato; 3: L = 2,2,6,6-tetramethyl-3,5-heptanedionato; 4: L = 3-methyl-2,4-pent …
Five diruthenium(II) complexes [Cl(L)Ru(mu-tppz)Ru(L)Cl] (1-5) containing differently substituted beta-diketonato derivatives (1: L = …
Intermediate-spin iron(IV)-oxido species with record reactivity.
Comba P, Nunn G, Scherz F, Walton PH. Comba P, et al. Faraday Discuss. 2022 May 18;234(0):232-244. doi: 10.1039/d1fd00073j. Faraday Discuss. 2022. PMID: 35156976 Free article.
The nonheme iron(IV)-oxido complex trans-N3-[(L(1))Fe(IV)O(Cl)](+), where L(1) is a derivative of the tetradentate bispidine 2,4-di(pyridine-2-yl)-3,7-diazabicyclo[3.3.1]nonane-1-one, has an S = 1 electronic ground state and is the most reactive nonheme iron model system known so …
The nonheme iron(IV)-oxido complex trans-N3-[(L(1))Fe(IV)O(Cl)](+), where L(1) is a derivative of the tetradentate bispidine 2,4-di(pyridine …
Carboxylate tolerance of the redox-active platform [Ru(mu-tppz)Ru](n), where tppz = 2,3,5,6-tetrakis(2-pyridyl)pyrazine, in the electron-transfer series [(L)ClRu(mu-tppz)RuCl(L)](n), n = 2+, +, 0, -, 2-, with 2-picolinato, quinaldato, and 8-quinolinecarboxylato ligands (L(-)).
Kundu T, Sarkar B, Mondal TK, Fiedler J, Mobin SM, Kaim W, Lahiri GK. Kundu T, et al. Inorg Chem. 2010 Jul 19;49(14):6565-74. doi: 10.1021/ic100500p. Inorg Chem. 2010. PMID: 20557093
The neutral title complexes [(L(1-3))ClRu(II)(mu-tppz)Ru(II)Cl(L(1-3))] [tppz = 2,3,5,6-tetrakis(2-pyridyl)pyrazine with L(1) = 2-picolinate, L(2) = 2-quinolinecarboxylate (quinaldate) and with the hitherto little used L(3) = 8-quinolinecarboxyl …
The neutral title complexes [(L(1-3))ClRu(II)(mu-tppz)Ru(II)Cl(L(1-3))] [tppz = 2,3,5,6-tetrakis(2-pyridyl)pyrazine wit …
98 results